Alice Rondo is one of five children summoned from another world to serve as Heroes. An unforeseen consequence of their summoning resulted in a magicule overflow within their bodies, granting them only a few years to live. Consequently, she was sent to Freedom Academy alongside other children sharing similar fates.
She possesses long blonde hair and red eyes, and is often seen in a pink dress, long black stockings, white gloves, and red shoes. Alice has a fondness for stuffed animals, with named companions such as Roosevelt, Peter, Oswald, and Garfield.
Her personality is smug and confident. She feels eternal gratitude toward Rimuru for saving her life. Originally, she was part of a group of students in Class S who gained a reputation as troublemakers following the departure of their first caretaker, Shizu.
At the academy, Shizu cared for her and the other children. After Shizu's death, their new teacher, Rimuru, engaged the class in a sparring match. During her turn, Alice unleashed a technique involving puppet manipulation but was quickly drained of energy.
Her life transformed when Rimuru took the children to the Republic of Ulgracia. There, at the Dwelling of the Elementals, she prayed at an altar and successfully merged with an artificial greater space elemental. This pact stabilized the rampant magicules within her, removing the imminent threat to her life.
Following this event, she and the others received new clothing sewn by Shuna. Alice was later invited to the Jura-Tempest Federation, where she took part in the country's Founding Festival. She eventually moved there permanently to continue her studies.
Among the summoned children, she was the one who initially impressed Rimuru the most. Her name is potentially a reference to the manga "Kagihime Monogatari Eikyū Alice Rondo."