Alfred is the academically inclined cousin of treasure hunter Montana Jones. He specializes in ancient cultures, languages, and historical treasures, possessing crucial expertise in deciphering ancient texts. Despite a strong aversion to danger, travel, and physical activities like swimming, he accompanies Montana on global expeditions to secure artifacts for museums.

His mentor, Professor Gerrit, supplies vital mission information primarily via gramophone records. During their travels, Alfred and Montana frequently receive assistance from Melissa Thorn, a multilingual reporter whose presence becomes a consistent part of their adventures. Alfred demonstrates domestic skills, regularly preparing spaghetti bolognese for the group, reflecting his preference for routine and comfort.

Family significantly defines his background; his mother, Agatha Jones (also Montana's aunt), appears in numerous episodes. A revelation in the final episode explains Melissa Thorn's recurring presence at critical moments through disclosed parentage, though Alfred's direct familial connections remain centered on his mother and cousin.

Within the trio, Alfred handles research and intellectual problem-solving, counterbalancing Montana's risk-oriented approach. Their differing temperaments create a functional dynamic. Their primary opposition comes from Lord Zero, an art-obsessed thief whose schemes disrupt their missions. Lord Zero employs subordinates Slim and Slam, along with the inventor Dr. Nitro; these figures interact with the group collectively, not specifically with Alfred individually.