"Dvine[LUV]" is a supernatural romance anime that intertwines themes of love, destiny, and the struggle between human emotions and divine intervention. The story centers around Aoi, a high school student who discovers she is the reincarnation of a celestial being tasked with maintaining the balance between the human world and the divine realm. Her memories of her past life begin to resurface after encountering Kaito, a mysterious transfer student who is revealed to be a fallen angel exiled from the heavens for defying divine laws.

As Aoi grapples with her dual identity, she learns that her role as a celestial guardian involves protecting humanity from malevolent spirits that seek to disrupt the harmony between worlds. Kaito, driven by his own unresolved emotions and a desire for redemption, becomes her reluctant ally. Their partnership is complicated by the growing emotional bond between them, which challenges the strict boundaries set by the divine order. The narrative explores their evolving relationship as they confront various supernatural threats, each encounter revealing more about their intertwined fates and the consequences of defying celestial mandates.

The series introduces a supporting cast of characters, including other celestial beings and humans with unique connections to the divine realm. Among them is Sora, a childhood friend of Aoi who harbors unspoken feelings for her and becomes entangled in the supernatural conflicts. Additionally, the enigmatic council of celestial overseers serves as both a guiding force and an antagonistic presence, enforcing the rules that Aoi and Kaito continually test. The plot delves into themes of free will, sacrifice, and the blurred lines between duty and desire, as the characters navigate their roles in a world where divine intervention and human emotions collide. The story builds toward a climactic confrontation that forces Aoi and Kaito to make pivotal choices about their destinies and the future of both realms.